Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN 2){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ3 O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1)
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چکیده
In the title compound, [Co(C11H12NO6P)(C6H5N3)2]·C6H5N3, the 2,2'-[N-(phenyl-phospho-rylmethyl-κO)aza-nedi-yl]di-acetate dianion N,O,O',O''-chelates the CoII cation and two 1H-benzo[d][1,2,3]triazole mol-ecules coordinate to the CoII cation to complete the slightly distorted octa-hedral coordination. In the crystal, classical O-H⋯O, N-H⋯O hydrogen bonds and weak C-H⋯N hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular architecture. π-π stacking between the triazole and benzene rings and between the benzene rings is also observed in the crystal.
منابع مشابه
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